The number of casts to get a full stack going might also be of interest. A negative binomial distribution (see
http://en.wikipedia.org/wiki/Negativ...l_distribution) gives the mean number of failures before r successes as r(1-p) / p, thus (after adding 5 successes):
Points in talent : Mean number of casts to stack winter's chill to 5
0: n/a
1: 25
2: 12.5
3: 8.33
4: 6.25
5: 5
You could also investigate the rogue dps spreadsheet's modelling of deadly poison, I believe it uses a poisson distribution (the negative binomial converges to the poisson) to model a very similar mechanic.