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Lets say you have a non-crit non-miss DPS of D.
1% hit will add 1% of D to your end damage. It takes 15 hit rating to get here, so it will add 1/15% damage per rating point.
1% crit will add 1.3% of D to your end damage with Mortal Shots. It takes 22 hit rating to get here, so it will add 1.3/22% damage per rating point.
1/15 = .0666
1.3/22 = .0591
So it's slightly better to get hit rating than crit rating. However, as has been pointed out, hit rating is cheaper in itemization, so yeah...what Glaurong said.
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