Originally Posted by Sapa
Not sure for Doomwalker, but since it "looks" like reaver I'd say he is immune too.
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Assuming it's the same mechanic as rogue poisons, they'll work fine on Doomwalker but not on Void Reaver. Other mobs I've noted as being poison immune are the Curator in Kara and Vashj's elemental adds (but not like those matter for purposes of this discussion).
The whole elemental/mechanical thing is annoyingly arbitrary at times since while Hydross is immune to poisons entirely in both phases, they work fine on Al'ar + adds and Murmur.