Originally Posted by Caldar
You only cap at 60fps if you have VSync enabled, but for the most part the human eye can't tell the difference from higher fps anyway.
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Disabling Vsync makes the game crank out images as fast as it can, but it doesn't make the monitor refresh faster than you've set it to.
If your computer can run WoW at the refresh frequency you've set, disabling Vsync only gives you tearing. It has little use outside of benchmarking really.
If 60fps isn't enough for you, crank up the refresh frequency instead.