1. VT
2. SW:P
3. MB
4. SW
5. MF
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I would argue that you want the following priority list to maximize dps.
1. SW
2. MB
3. VT
4. SW:P
5. MF
Outside of the initial SW:D or mb (depending if it's safe at the fight to SW:D), with 5/5 mb, using mb/SW:D every moment they are up - I rarely see either hit when vt is down. I do see them hit with SW:P down a tick, but you'll maximize your dps (maybe lose a slight bit of mana, but I never really go oom if I'm using pot cd's every time I'm below 2k mana and they're up).
Like I said - that's just me, and is from experience - but anything with a cd like SW:D/mb, you want to use first and keep using to maximize their usage.
Even after using a skull of gul'dan, they're worth using (and eating the bit of gcd you get) due to their supremely higher dps.