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The difference is, netherweave is extremely easy to farm. Every single humanoid mob in the 64+ outlands areas are what you could consider a "node" for netherweave. Azeroth herb / mining nodes on the other hand, have a fairly limited supply, with the added burden of limited to 120% max mount speed for a paladin, 110% for other classes.
Edit:
Before the patch that took arcanite off the transmute cooldown, I was able to make a decent chunk off my leveling alchemist by making an arcanite bar every day, since all paladins need them for the lvl 60 mount quest, which a lot of people are interested in. This also has the added benefit of removing ~25-30 levels of alchemy skillups from your herb stockpile. While there isn't a cooldown on it anymore, you can still possibly make a few gold if you see someone in trade asking around for arcanite bars.
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