Originally Posted by Sapphidia
You have an enchant that works like the Shattered Sun Scryer Necklace proc. That is, a high proc chance, and internal cooldown (50% and 20 seconds is the implication so far). The fact that a proc from this deathfrost enchant is an identical bolt to the melee one is kind of inconsequential, it seems its treated totally separately.
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Game database sites seem to confirm the 50% proc chance for spells.
Deathfrost - Spell - World of Warcraft