Originally Posted by Faldrath
No. As far as I remember (it's been a while since I last had a MSD), it can proc from the initial application of the dot, but not from subsequent ticks.
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Spell Focus Trigger - Spell - World of Warcraft
It shows that it only procs of actual casts, and a dot tick clearly is not.
Since the nerf this gem is not really good for basicaly anyone. I would use the Chaotic Skyfire Diamond in most/all cases.