Looking at this thread:
http://forums.worldofwarcraft.com/th...hreadID=518526
And specifically the post about nefarian's loot table.
Item Slot 1:
Common 20% each
-Pure elementium band
-Therazines
-Neltharions tear
-Boots
Rare 10% each
-Staff of shadow flame
-Asscandy
Item Slot 2:
Common 20% each
-Ring of Reck
-Prestors talisman
-Cloak of broodlord
-Mindflayer Hat
Rare 10% each
-Crul axe
-Lok'amir
This does seem to indicate that, for example, you can't get 2 items from group 2 on the same kill (ie ring of reck and the prestors). I always assumed all nonset items A-L were assigned probabilites, random rolled, and awared to slot 1 and 2, and if 2 matched 1, 2 was rerolled. Then any combination of 2 items would be theoratically possible.
It certainly seems odd how this model was used for nonset items, but not for set items. (A comparable model for set items would be putting chests 1-4 in item slot 1, and chests 5-8 in item slot 2, which would make duplicates impossible. Obviously this is not the case.). It also seems odd how duplication was acceptable for the set pieces but not the itemset.
I did some poking through other guilds nef kills, and I never saw any contradictions to the above (ie a kill with multiple item slot 2 items).
Ragnaros seems even odder; every time I have seen eye/BRE/Spinal drop it has been a 5th epic instead of occupying one of the standard 4 slots.
Does anybody else have any other evidence or information about these "item slot" groupings? Chromaggus I assume would have something similar to nefarian as he drops 4 epics. The bosses that drop 3 epics (2 set + 1 nonset) seem pretty simple (roll twice for set, the roll the nonset table).