I had old versions of charts indicating bite order for 10 and 25 man as well as the alternate (and then optimal) strategies using a sacrificed player. Now that is entirely unnecessary and I've updated the charts to reflect it coinciding perfectly with the 5:15 enrage timer.
In regards to the first bite mechanic, we tried several things to try and figure out the order. According to our experiences:
-It does not seem to be the player that has done the most damage by the 15 second mark.
Reasoning: I was highest and the second or 3rd highest was bitten. During these times I was not Misdirecting to the tank to try to be second in threat which means I wasn't hitting Blood Queen for the first ~2 seconds of the pull.
-It does not seem to be first on threat after the tank.
Reasoning: We had the other DPS delay popping cooldowns for the first 15 seconds except for me, and I was second in threat at all times after the pull up to the bite and was not chosen.
-It -may- be the related to something about the first hit on Lana'thel, however I can not explain how healers would have been bitten first.
Reasoning: We did get our last 4 pulls of the night to all have me bitten first. On the 3-2-1 countdown I was Misdirecting the tank and landed my initial Serpent Sting at "2" on the countdown to be sure to be the first non-tanking player to land an offensive ability and initiate the pull (rather than proximity aggro of the incoming main tank).
My only explanation of why a healer was bitten would be do to possibly a Judgement landing first or possibly the tank actually getting hit by the first melee swing and then technically the first non-npc ability to register threat was a HoT or if a buff proc possibly registered. But regardless, I can't really come up with a satisfactory reasoning behind it.