Originally Posted by Pillion
I understand that the reason instant is on the MH because it will hit for more damage. Taking it off the MH could be a DPS loss but a high hit / mastery rating could make up or be a DPS increase.
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No, that's incorrect. Instant is on the main hand due to
PPM (procs per minute) mechanics. The slower the weapon, the greater the chance the poison will proc, resulting in better numbers than the static chance of deadly procing.