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You need 12.6 Spell Hit Rating at Level 70 per 1%. Bosses have a 17% chance to be missed with spells. Now, since spells have a 1% miss cap that we can never get rid of, you need +16% Spell Hit.
12.6 x 16 = 202 Spell Hit Rating (rounded up from 201.6) to completely negate the miss rate.
However, please note, that the number 202 is only if you have NO +spellhit talents in your build (extremelly unlikely). You need to take those into account before figuring out exactly how much Spell Hit Rating you need to cap out on bosses.
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