Indeed the Collar is (very) superior point by point. Having no red sockets and a +spell damage socket bonus is a bit annoying for me though. I would clearly shift from SS hood to this Collar if I got it - I'd also guess I might have found a legs slot improvement at this time, thus in summation upgrading well above the 2 piece set bonus too. Assuming that a cast rate of 3 spell hits in an average 10 second proc duration, SS set bonus proc boils down to 12 +dmg per spell hit (92*(3/23), 3 out of 23 hits, given that the 5% proc rate is correct). Scorch spam could ofc put you up to 6-7 spell hits in a 10sec period, but the lower +dmg coefficient would effectively bring it back down. Sorry if I'm being a bit fire mage specific here
This being said, I think a more interesting competition would be the
Collar versus the new
Destruction Holo-Gogs.