Originally Posted by Renato
That doesn't make any sense. If Serpent Sting is more damage per global and more damage per focus than Arcane Shot then it is obvious that using Serpent Sting over Arcane Shot on any target would be a better use of your 1 global. Even if you do not maintain the Serpent Sting just applying it and letting it tick for the 15 seconds on a secondary target would provide a higher amount of damage per focus and per global than any other ability you can use.
Now the real question that comes up is how many targets before Multi-Shot every 4 seconds is better than just simply tab Serpent Stinging?
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You are indeed correct. As I stated in a reply in the Simple Answers thread, SrS on a target with no debuffs still does about twice the damage of an AS on a fully debuffed target and costs less focus by 5. Hence, almost anytime you can substitute a SrS on a secondary target for an AS on the primary target is a DPS gain and benefit to the raid. The exceptions include when it is important to kill the primary target ASAP, where any damage on the secondary targets is wiped away by that target being at full health when it becomes the primary target, or where the secondary target will die before the SrS ticks more than a couple ticks. Even in the later case, a SrS to kill the target is still more efficient focus wise than a AS, although it takes longer for the kill.
My analysis indicates that it is only benefitial to maintain SrS on up to 2 secondary targets that are grouped in AoE situation, but that it can still be beneficial to hit additional targets if they are spread out and you do not lose significant attack time from the switching of targets to cast the SrS on them.
For group AoE, SrS does not make sense to use if the group has 4 or more targets. The MS damage on the targets overweighs the benefits of spending GCDs to switch targets and SrS them up. If you have BW available during the AoE situation, then ignoring SrS for more MSs is even more important.
Thus, the situation is pretty similar to before the SrS buff. Use MS to AoE if there are 4 or more targets, otherwise you are better off doing single target DPS with the addition now of SrS up to 3 targets. including the primary target.