Originally Posted by Litvan
So since most of my gear has +exp it recommends mastery, completely disregarding the exp cap for a boss to dodge an attack? (sorry for a "nub" question, but if it does that makes little sense to me that it'd disregard the exp cap)
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The EP weights are a calculation of the relative DPS increase per stat. So, for Assassination, the increase in poison damage from mastery is a greater DPS increase per stat than the damage lost from a lack of expertise (being dodged). Aldriana's comment about mastery heavy gear meant, that with the weights that Shadowcraft produces, and thereby theoretically the highest DPS, the only time you would expertise cap would be if a lot of your gear pieces naturally had mastery on them (which would mean the next most valuable stat to reforge to would be expertise).
Essentially, for Assassination, expertise is just less valuable for DPS than mastery.